The dmg coordinates to Zn(II) ions as a tridentate ligand (μ-η 1:η 1:η 0:η 1 coordination mode) and displays an unprecedented coordination mode (Scheme S1.). The carboxylate groups presented in the structure of the dmg ligand exhibit different coordination modes and are attached to Zn(II) ions with monodentate and chelate. Furthermore, a pair of dmgH- ligands are joined through hydrogen bonds to give a macrocyclic ligand. The most famous complex is the bright red Ni(dmgH)2, formed by treatment of Ni(II) sources with dmgH2. Dmg is tri or bidentate ligand? It is a bi dentate ligand although it is an unsymmetrical ligand but its square planar complex can not show geometrical isomerism becoz of intra molecular H. Dmg is a strong field ligand or a weak field ligand - Chemistry - Coordination Compounds.
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